Scientific provenance
The chain does not stop at the measurement. A result is cited in a figure, a figure goes into an article, and it must be possible to start from the article and find the sampling, the digestion protocol and the exact row of the instrument export. This page describes the three node natures, what they change about the shape of the graph, and the tools the AI assistant receives.
Three node natures
| Nature | What it is | Behaviour |
|---|---|---|
| Aliquot | Material. | Is transformed and consumed. |
| Result | A measured value. | Is no longer transformed, but is cited. |
| Output | A figure, a table, an article. | Cites results. |
That distinction governs the shape of the graph. Upstream of a result it is a lineage: material does not duplicate. Downstream it is a network: the same delta appears in three figures, and the same figure cites forty. The two meet exactly at the result node, which rules out any cycle.
The value of a result
The value is structured, not written as a string. A value written "δ53Cr = -0.12 ± 0.05 ‰" cannot be compared or converted, and has to be parsed again before anything can be done with it.
Output and reference
An output carries a reference: a local identifier, plus a title, a DOI and a year that survive the sharing of the folder. A publication identifier is local to one database; the title and the DOI stay readable for the recipient.
There is no single rule
A figure may point straight at the deltas, or be produced from a synthesis workbook. Both practices exist and the model can express both: in the first case these are edges from result nodes, in the second it is a file attached to the figure node. Both go back to the weighing, the second through the workbook's own attachments, which already carry their locators.
A complete example
From the article, walking up reaches the raw material and picks up the digestion protocol five steps higher, along with the measurement export and its exact row. From the sample, the symmetric question returns the outputs that cite it, and only those.
The assistant's tools
Three read-only tasks are declared, and are therefore available even in conversation mode.
| Task | Role |
|---|---|
| core.provenance_resoudre | Translates a spoken name, "BCR-723", into concrete nodes, across the known campaigns. |
| core.provenance_recit | Returns the lineage of a node in working order, from sampling towards the result. |
| core.provenance_comparer | Returns what differs between two nodes, and nothing else. |
What the comparison does
| Point | Behaviour |
|---|---|
| Alignment | On the step, not on the rank. Otherwise a digestion would be compared to a purification as soon as one chain has an extra step. |
| Files | Compared by path, not by locator: two samples from the same export normally differ by the row. |
| Identical steps | Stated. Without them, a model concludes that everything differs. |
| Value gap | Refused between two different quantities or units. Returned in combined standard deviations, with a compatibility verdict at 2σ. |
| No difference | That is an answer, not a failure: it says the cause lies elsewhere. |
Every output is bounded, forty nodes, thirty steps, twenty-five files, and truncation is announced. A model receiving a cut list without knowing it concludes that the chain starts there.
Links in answers
Files and nodes cited in an assistant answer become clickable. Only what appears word for word in the result of a tool actually called during that message becomes a link. Scanning the prose for anything that looks like a file name would catch more mentions and produce dead links, which are worth less than no link at all in traceability software.
A link is marked by a dotted underline rather than by colour alone. A tool call that errored attests nothing and produces no link; a node whose campaign is unknown is not clickable, a link to the wrong campaign being worse than no link.
What the model is not asked to do
Detecting inconsistencies, for instance between a dilution factor and an injected concentration, is not handed to the model. It is arithmetic: a rule does it, explains its verdict by showing both numbers and where they came from, and returns the same result tomorrow. The cost of a false positive is decisive, since after three wrong alerts on thesis data every alert is ignored, including the right one.
What is missing first is therefore not assistance but the model of quantities: masses, volumes and dilutions with their units. Once those rules are written, the model has its role: explaining an alert in plain language.