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Contaminated grassland soils around the Lengerich cement plant (profiles 1 to 3)

North Rhine-Westphalia, Lengerich (Steinfurt district), Germany

Soils

Type
Soil

Late-1970s Tl pollution from a cement plant near Lengerich, which added Tl-rich Meggen pyrite roaster calcines to the raw meal as an iron corrective; deposition estimated up to 400 µg/m²/d, leaf necrosis and alopecia in livestock, stopped in 1979. Three grassland profiles down to 1 m, numbered by increasing distance from the plant, on marly moraine till. Total and exchangeable Tl highest at the surface and decreasing with depth (addition profiles); ε205Tl and 1/[Tl] aligned (r² = 0.82) between an emission end-member near 0 (Tl above 2 mg/kg) and a geogenic background near -4 (0.1 to 0.2 mg/kg), possibly inherited from marine carbonates; exchangeable Tl rises from 2 % at depth to 17 % at the surface (Kersten et al., 2014). Indicative coordinates (Lengerich town): profile locations shown only on a figure.

ε205Tl in ε units (parts per 10,000) Values of the same system

Standard : NIST SRM 997

ValueRangenMineral or matrixSource
−0.08 ± 0.35 εsoil of profile 1, 0-10 cm
Published mean of 2 to 4 analyses; ± 0.35 ε (2 SD); 3.17 ± 0.43 mg/kg Tl, of which 0.554 ± 0.045 mg/kg extractable with 1 M NH4NO3; heaviest and most Tl-rich soil value, identical to the kiln dust.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−1.56 ± 0.35 εsoil of profile 1, 10-30 cm
Published mean of 2 to 4 analyses; ± 0.35 ε (2 SD); 0.72 ± 0.08 mg/kg Tl, of which 0.086 ± 0.010 mg/kg extractable with 1 M NH4NO3.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−2.55 ± 0.4 ε1soil of profile 1, 30-40 cm
Single analysis; ± 0.4 ε (2 SD); 0.23 ± 0.02 mg/kg Tl, of which 0.020 ± 0.002 mg/kg extractable with 1 M NH4NO3.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−0.88 ± 0.4 ε1soil of profile 2, 0-10 cm
Single analysis; ± 0.4 ε (2 SD); 2.27 ± 0.18 mg/kg Tl, of which 0.243 ± 0.014 mg/kg extractable with 1 M NH4NO3.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−1.69 ± 0.4 ε1soil of profile 2, 10-30 cm
Single analysis; ± 0.4 ε (2 SD); 1.64 ± 0.29 mg/kg Tl, of which 0.150 ± 0.012 mg/kg extractable with 1 M NH4NO3.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−2.31 ± 0.35 εsoil of profile 2, 30-50 cm
Published mean of 2 to 4 analyses; ± 0.35 ε (2 SD); 0.63 ± 0.03 mg/kg Tl, of which 0.074 ± 0.004 mg/kg extractable with 1 M NH4NO3.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−3.59 ± 0.35 εsoil of profile 2, 50-90 cm
Published mean of 2 to 4 analyses; ± 0.35 ε (2 SD); 0.21 ± 0.04 mg/kg Tl, of which 0.007 ± 0.002 mg/kg extractable with 1 M NH4NO3; geogenic background.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−3.61 ± 0.35 εsoil of profile 2, 90-100 cm
Published mean of 2 to 4 analyses; ± 0.35 ε (2 SD); 0.15 ± 0.02 mg/kg Tl, of which below 0.001 mg/kg extractable with 1 M NH4NO3; C horizon of the marly till, geogenic background.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−2 ± 0.4 εsoil of profile 3, 0-10 cm
Published mean of 2 to 4 analyses; ± 0.4 ε (2 SD); 0.92 ± 0.06 mg/kg Tl, of which 0.063 ± 0.006 mg/kg extractable with 1 M NH4NO3.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−2.59 ± 0.35 ε1soil of profile 3, 10-30 cm
Single analysis; ± 0.35 ε (2 SD); 0.46 ± 0.02 mg/kg Tl, of which 0.021 ± 0.003 mg/kg extractable with 1 M NH4NO3.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…
−4.17 ± 0.4 εsoil of profile 3, 30-40 cm
Published mean of 2 to 4 analyses; ± 0.4 ε (2 SD); 0.16 ± 0.01 mg/kg Tl, of which 0.006 ± 0.001 mg/kg extractable with 1 M NH4NO3; lightest value, geogenic background.
Kersten et al. (2014), Tracing anthropogenic thallium in soil using stable isotope compos…

Deposits of the same type

Cite this page

IsoFind Atlas (2026). Contaminated grassland soils around the Lengerich cement plant (profiles 1 to 3), isotope signatures. https://www.isofind.tech/isotopes/en/sites/sols-de-prairie-contamines-autour-de-la-cimenterie-de-lengerich-profils-1-a-3/ (accessed 2026-10-16).

@misc{isofind2026contaminatedgrasslandsoilsaro,
  title = {Contaminated grassland soils around the Lengerich cement plant (profiles 1 to 3), isotope signatures},
  author = {{IsoFind Atlas}},
  year = {2026},
  url = {https://www.isofind.tech/isotopes/en/sites/sols-de-prairie-contamines-autour-de-la-cimenterie-de-lengerich-profils-1-a-3/},
  note = {Accessed 2026-10-16}
}

Updated : 2026-10-16