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Salar de Olaroz

Jujuy Puna, Argentina

OtherLi (K, B)

Type
Continental salar brine

Salar of the Argentine Puna worked for lithium (Orocobre) by pumping deep brines. Lithium comes from weathering of the basin ignimbrites and metasediments and from a hydrothermal input. Evaporation concentrates lithium by two to three orders of magnitude without measurable fractionation; at depth, adsorption of 6Li onto clays and iron oxyhydroxides makes the brines heavier, while ancient brines and smectite desorption offset the lithium loss.

δ7Li in ‰ (per mil) Values of the same system

Standard : L-SVEC

ValueRangenMineral or matrixSource
6.58 ± 0.55 ‰5.9 / 7.2 ‰5shallow brine (about 0.6 m)
Mean and standard deviation recalculated from 5 samples in Table 1; Li from 419 to 891 mg/L.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
9.4 ± 0.75 ‰8.1 / 10.3 ‰15deep brine (200 to 450 m)
Mean and standard deviation recalculated from 15 samples in Table 1; Li from 692 to 1488 mg/L. The abstract gives +8.1 to +10.2 ‰, but PP11 is +10.3 ‰ in the table.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
6.05 ± 0.64 ‰5.6 / 6.5 ‰2surface halite crust
Two samples (northern and central transects), Table 2; Li 70 and 219 mg/kg. Signature close to that of shallow brines.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
−4.1 ± 3.95 ‰−7 / 0.4 ‰3basin ignimbrites (Toro, Coranzulí)
Mean and standard deviation of 3 samples, Table 2; Li from 61 to 92 mg/kg, the highest contents among basin rocks.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
−7.15 ± 7 ‰−13.9 / 0.5 ‰4volcanic tuffs and ashes (Sijes and Pastos Chicos formations)
Mean and standard deviation of 4 samples, Table 2. The abstract gives -13.8 ‰ for the lowest value, the table -13.9 ‰ (FS-TA).
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
−12.5 ‰1biotite-rich layer of the Sijes Formation
One analysis (FS-BIOT), Table 2; 44 mg/kg Li.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
−5.7 ‰1Ordovician host metasediments
One analysis (A18), Table 2; 43 mg/kg Li.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…

87Sr/86Sr isotope ratio, no unit Values of the same system

Standard : NIST SRM 987

ValueRangenMineral or matrixSource
0.71466 ± 0.000840.7134 / 0.71514shallow brine
Mean and standard deviation of 4 samples, Table 1.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
0.71484 ± 0.00020.71459 / 0.7152116deep brine
Mean and standard deviation of 16 samples, Table 1. Values intermediate between thermal waters (about 0.717) and basin rocks (about 0.712).
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
0.71196 ± 0.000220.7118 / 0.712112Toro ignimbrite
Two samples, Table 2.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
0.71392 ± 0.001620.71278 / 0.715072Sijes Formation tuffs
Two samples, Table 2.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
0.71268 ± 0.000970.7116 / 0.713964Sijes Formation sediments
Mean and standard deviation of 4 samples (sands, clays, biotite layer), Table 2.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…
0.71348 ± 0.002580.71101 / 0.716545Trinchera Formation fluvial sediments
Mean and standard deviation of 5 samples, Table 2.
Garcia et al. (2020), Characterization of lithium cycling in the Salar De Olaroz, Central…

Deposits of the same type

Cite this page

IsoFind Atlas (2026). Salar de Olaroz, isotope signatures. https://www.isofind.tech/isotopes/en/deposits/salar-de-olaroz/ (accessed 2026-10-13).

@misc{isofind2026salardeolarozisotopesignature,
  title = {Salar de Olaroz, isotope signatures},
  author = {{IsoFind Atlas}},
  year = {2026},
  url = {https://www.isofind.tech/isotopes/en/deposits/salar-de-olaroz/},
  note = {Accessed 2026-10-13}
}

Updated : 2026-10-13