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Niujuan

Hebei, Fengning (North Hebei metallogenic belt, northern margin of the North China Craton), China

Other hydrothermalAg (Pb, Zn)

Type
Breccia-hosted silver related to subvolcanic intrusions

Reserve of 652 t Ag at 277.85 g/t in five breccia bodies along the Niujuan-Laohuba fault, at the contact of Mesozoic granites (Baiyingou, Hercynian; Er'daogou, 145.5 ± 2.1 Ma by zircon U-Pb) and the Hongqiyingzi metamorphic group. Four stages: quartz (I), quartz-pyrite (II), polymetallic sulfides with argentite and native silver (III, main) and fluorite (IV, Sm-Nd isochron of 139.2 ± 3.8 Ma, initial Nd 0.511785). Li et al. (2017): deep sulfur and lead, magmatic fluid mixed with meteoric water, 12 to 61 % mantle helium. Indicative coordinates: about 38 km north of Fengning town from Figure 1c of Li et al. (2017), to within 15 km.

δ34S in ‰ (per mil) Values of the same system

Standard : V-CDT

ValueRangenMineral or matrixSource
3.6 ± 1.1 ‰2.6 / 4.7 ‰3stage II and III pyrite
Mean and standard deviation recalculated from 3 analyses, +2.6 to +4.7 (1-73-5 (stage II) +2.6; 1-77-6 (stage II) +3.6; 5-71-3 (stage III) +4.7). Published pyrite mean +3.6 ‰. Sulfides from 1150 to 1190 m depth.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…
2.8 ± 0.5 ‰2.4 / 3.1 ‰2stage III galena
Mean and standard deviation recalculated from 2 analyses, +2.4 to +3.1 (5-73-5(Gn) (stage III) +2.4; 5-73-4(Gn) (stage III) +3.1). Published galena mean +2.8 ‰. Sulfides from 1150 to 1190 m depth.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…
5.3 ± 0.1 ‰5.2 / 5.3 ‰2stage III sphalerite
Mean and standard deviation recalculated from 2 analyses, +5.2 to +5.3 (5-73-5(Sp) (stage III) +5.2; 5-73-4(Sp) (stage III) +5.3). Published sphalerite mean +5.3 ‰. Sulfides from 1150 to 1190 m depth.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

206Pb/204Pb isotope ratio, no unit Values of the same system

Standard : Non précisé dans la publication

ValueRangenMineral or matrixSource
16.894 ± 0.04216.837 / 16.9327stage II and III pyrite, galena and sphalerite
Mean and standard deviation recalculated from 7 analyses, 16.837 to 16.932 (1-73-5 (pyrite, stage II) 16.930; 1-77-6 (pyrite, stage II) 16.932; 5-71-3 (pyrite, stage III) 16.925; 5-73-5(Gn) (galena, stage III) 16.837; 5-73-5(Sp) (sphalerite, stage III) 16.917; 5-73-4(Sp) (sphalerite, stage III) 16.875; 5-73-4(Gn) (galena, stage III) 16.841). Δβ and Δγ calculated at 139 Ma in the mantle lead field according to the authors.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

207Pb/204Pb isotope ratio, no unit Values of the same system

Standard : Non précisé dans la publication

ValueRangenMineral or matrixSource
15.477 ± 0.03715.42 / 15.5317stage II and III pyrite, galena and sphalerite
Mean and standard deviation recalculated from 7 analyses, 15.420 to 15.531 (1-73-5 (pyrite, stage II) 15.501; 1-77-6 (pyrite, stage II) 15.477; 5-71-3 (pyrite, stage III) 15.499; 5-73-5(Gn) (galena, stage III) 15.445; 5-73-5(Sp) (sphalerite, stage III) 15.531; 5-73-4(Sp) (sphalerite, stage III) 15.465; 5-73-4(Gn) (galena, stage III) 15.420). Δβ and Δγ calculated at 139 Ma in the mantle lead field according to the authors.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

208Pb/204Pb isotope ratio, no unit Values of the same system

Standard : Non précisé dans la publication

ValueRangenMineral or matrixSource
37.785 ± 0.12437.599 / 37.9537stage II and III pyrite, galena and sphalerite
Mean and standard deviation recalculated from 7 analyses, 37.599 to 37.953 (1-73-5 (pyrite, stage II) 37.872; 1-77-6 (pyrite, stage II) 37.800; 5-71-3 (pyrite, stage III) 37.860; 5-73-5(Gn) (galena, stage III) 37.665; 5-73-5(Sp) (sphalerite, stage III) 37.953; 5-73-4(Sp) (sphalerite, stage III) 37.748; 5-73-4(Gn) (galena, stage III) 37.599). Δβ and Δγ calculated at 139 Ma in the mantle lead field according to the authors.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

δ18O in ‰ (per mil) Values of the same system

Standard : V-SMOW

ValueRangenMineral or matrixSource
2.53 ± 1.08 ‰0.6 / 4.15 ‰10stage I and II quartz
Mean and standard deviation recalculated from 10 analyses, +0.60 to +4.15 (1-79-4 (stage II, Li et al., 2017) +0.60; 9-78-2 (stage II, Li et al., 2017) +2.50; 9-72-4 (stage I, Li et al., 2017) +3.00; 82lineCM3 (stage I, Li and Geng, 1997) +1.31; ZK83-1 (stage I, Li and Geng, 1997) +2.78; ZK79-3 (stage I, Li and Geng, 1997) +2.62; 82lineCM3 (stage I, Li and Geng, 1997) +4.15; 82lineCM3 (stage I, Li and Geng, 1997) +2.13; TC80 (stage I, Li and Geng, 1997) +2.21; TC82 (stage I, Li and Geng, 1997) +4.01). Water δ18O: 1-79-4 -7.05 ‰ at 280 °C; 9-78-2 -5.15 ‰ at 280 °C; 9-72-4 -3.89 ‰ at 300 °C; 82lineCM3 -5.58 ‰ at 300 °C; ZK83-1 -4.11 ‰ at 300 °C; ZK79-3 -4.27 ‰ at 300 °C; 82lineCM3 -2.74 ‰ at 300 °C; 82lineCM3 -4.76 ‰ at 300 °C; TC80 -4.68 ‰ at 300 °C; TC82 -2.88 ‰ at 300 °C. 82lineCM3 appears three times (one analysis from Li et al., 2017, two from Li and Geng, 1997). The abstract prints "0.6 to -4.15 ‰" for values that are all positive.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

δD in ‰ (per mil) Values of the same system

Standard : V-SMOW

ValueRangenMineral or matrixSource
−108.9 ± 7.6 ‰−119.4 / −98.7 ‰7fluid-inclusion water in stage I and II quartz
Mean and standard deviation recalculated from 7 analyses, -119.4 to -98.7 (1-79-4 (stage II, Li et al., 2017) -104.3; 9-78-2 (stage II, Li et al., 2017) -113.2; 9-72-4 (stage I, Li et al., 2017) -119.4; 82lineCM3 (stage I, Li and Geng, 1997) -98.7; ZK83-1 (stage I, Li and Geng, 1997) -104.8; ZK79-3 (stage I, Li and Geng, 1997) -116.9; 82lineCM3 (stage I, Li and Geng, 1997) -105.0). Mixture of magmatic and meteoric water according to the authors, the meteoric share increasing towards the late stages.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

3He/4He (R/Ra) isotope ratio, no unit Values of the same system

Standard : Air (Ra = 1,4 × 10⁻⁶) : valeurs en R/Ra

ValueRangenMineral or matrixSource
2.24 ± 2.2290.921 / 4.8143pyrite fluid inclusions
Mean and standard deviation recalculated from 3 analyses, 0.921 to 4.814 (1-77-6 0.986; 5-71-3 0.921; 9-75-1 4.814). R/Ra calculated from the Table 6 3He/4He (× 10⁻⁶: 1-77-6 1.38; 5-71-3 1.29; 9-75-1 6.74) with Ra = 1.4 × 10⁻⁶ as the authors do (0.921 to 4.81 Ra in the text). Mantle helium from 11.56 to 61.20 %; 4He from 0.09 to 1.26 × 10⁻⁷ cm3 STP/g.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

40Ar/36Ar isotope ratio, no unit Values of the same system

Standard : Air (40Ar/36Ar = 295,5)

ValueRangenMineral or matrixSource
301.98 ± 2.35299.34 / 303.843pyrite fluid inclusions
Mean and standard deviation recalculated from 3 analyses, 299.34 to 303.84 (1-77-6 303.84; 5-71-3 299.34; 9-75-1 302.75). Close to air: air-saturated meteoric water argon according to the authors.
Li et al. (2017), Isotope geochemistry and geochronology of the Niujuan silver deposit, n…

Deposits of the same type

Cite this page

IsoFind Atlas (2026). Niujuan, isotope signatures. https://www.isofind.tech/isotopes/en/deposits/niujuan/ (accessed 2026-10-22).

@misc{isofind2026niujuanisotopesignatures,
  title = {Niujuan, isotope signatures},
  author = {{IsoFind Atlas}},
  year = {2026},
  url = {https://www.isofind.tech/isotopes/en/deposits/niujuan/},
  note = {Accessed 2026-10-22}
}

Updated : 2026-10-22