San Juan de Plan
Aragon (Huesca), Axial Zone of the Central Pyrenees, Spain
Other hydrothermalCo (Ni)
- Type
- Hydrothermal Co-Ni arsenides and sulpharsenides
Axial Zone of the Spanish Central Pyrenees (Huesca and Lleida), Co-Ni arsenide, diarsenide and sulpharsenide deposits in the hanging wall of thin-skinned thrusts (Gavarnie nappe, Nogueras thrust sheets), footwall of Variscan black shales; formed between 300 and 600 °C. Sm-Nd age of ore-stage ankerites of 86 ± 27 Ma (Late Cretaceous), coeval with Pyrenean high-temperature low-pressure metamorphism, mantle exhumation and alkaline magmatism. Fluid of magmatic origin masked by interaction with black shales and carbonates, sulphur and metals leached from the Variscan basement and the underlying black shales according to Manuel et al. (2018). Ankeritised carbonate horizon 500 m long and up to 2 m thick on top of Silurian black shales (autochthonous units of the Gavarnie nappe), below the Triassic red beds, controlled by E-W fractures; decimetric pockets, disseminations and veinlets, locally in porphyritic granite dykes; four stages (Fe sulphides and sulpharsenides, Co-Ni arsenides and sulpharsenides, Co triarsenides, late Fe-Bi-Cu-Co stage). Sulphur partly from the local black shales. Indicative coordinates (San Juan de Plan village).
δ13C in ‰ (per mil) Values of the same system
Standard : V-PDB
| Value | Range | n | Mineral or matrix | Source |
|---|---|---|---|---|
| −4.27 ± 0.12 ‰ | −4.4 / −4.2 ‰ | 3 | pre-ore fine-grained replacement dolomite Mean and standard deviation recalculated from 3 analyses. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
| −4.92 ± 0.37 ‰ | −5.4 / −4.5 ‰ | 5 | ore-stage sparry ankerite Mean and standard deviation recalculated from 5 analyses. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
| −2.4 ‰ | 1 | Silurian host limestone (SJ-44) Single analysis. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
δ18O in ‰ (per mil) Values of the same system
Standard : V-SMOW
| Value | Range | n | Mineral or matrix | Source |
|---|---|---|---|---|
| 16.03 ± 0.78 ‰ | 15.4 / 16.9 ‰ | 3 | pre-ore fine-grained replacement dolomite Mean and standard deviation recalculated from 3 analyses. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
| 16.74 ± 1 ‰ | 15.1 / 17.7 ‰ | 5 | ore-stage sparry ankerite Mean and standard deviation recalculated from 5 analyses, fluid +13.3 to +15.9 ‰ at 600 °C for the ankerites of both mines. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
| 15.3 ‰ | 1 | Silurian host limestone (SJ-44) Single analysis; 18O-depleted relative to Silurian seawater, meteoric diagenetic stabilisation. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
δ34S in ‰ (per mil) Values of the same system
Standard : V-CDT
| Value | Range | n | Mineral or matrix | Source |
|---|---|---|---|---|
| 12.69 ± 3.73 ‰ | 6.5 / 16.8 ‰ | 13 | gersdorffite Mean and standard deviation recalculated from 13 analyses, nine ESC samples, four of them analysed twice (suffix b); two sources, about +5 to +10 ‰ and above +12 ‰. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
87Sr/86Sr isotope ratio, no unit Values of the same system
Standard : NIST SRM 987
| Value | Range | n | Mineral or matrix | Source |
|---|---|---|---|---|
| 0.71262 ± 0.00076 | 0.71128 / 0.71309 | 5 | ore-stage ankerite, initial ratio at 86 Ma Mean and standard deviation recalculated from 5 analyses, εSr86 +97.7 to +126.1; measured ratios 0.71328 to 0.71512; crustal source (detrital and igneous basement). | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
εNd(t) in ε units (parts per 10,000) Values of the same system
Standard : CHUR
| Value | Range | n | Mineral or matrix | Source |
|---|---|---|---|---|
| −11.34 ± 0.23 ε | −11.6 / −11.1 ε | 5 | ore-stage ankerite Mean and standard deviation recalculated from 5 analyses, mine Sm-Nd isochron at 91 ± 38 Ma; both mines together at 86 ± 27 Ma (MSWD = 0.71), initial 143Nd/144Nd of 0.511957. | Manuel et al. (2018), Multi-isotope survey on the metallogenesis of the hydrothermal Co-N… |
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Cite this page
IsoFind Atlas (2026). San Juan de Plan, isotope signatures. https://www.isofind.tech/isotopes/en/deposits/san-juan-de-plan/ (accessed 2026-10-15).
@misc{isofind2026sanjuandeplanisotopesignature,
title = {San Juan de Plan, isotope signatures},
author = {{IsoFind Atlas}},
year = {2026},
url = {https://www.isofind.tech/isotopes/en/deposits/san-juan-de-plan/},
note = {Accessed 2026-10-15}
}Updated : 2026-10-15
