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Pampalo (Hattu schist belt)

North Karelia, Ilomantsi, Hattu schist belt, Finland

Orogenic goldAu

Type
Orogenic gold in tuffaceous metavolcanic rocks and felsic porphyries

Archaean schist belt (2.76 to 2.72 Ga) of the Karelian domain, with felsic to intermediate volcano-sedimentary rocks cut by tonalites, granodiorites and felsic porphyries; Au-Bi-Te gold in shear zones, older than the metamorphic peak (500 to 600 °C, 3 to 5 kbar, about 2.70 Ga). Active mine (reserve 0.505 Mt at 2.31 g/t); gold mainly in a tuffaceous intermediate metavolcanic unit cut by felsic porphyries along the Pampalo shear zone, albite-K-feldspar-biotite-sericite-carbonate alteration. Molnár et al. (2016): tourmaline δ11B, sulphide δ34S and chalcopyrite δ65Cu.

δ11B in ‰ (per mil) Values of the same system

Standard : NIST SRM 951

ValueRangenMineral or matrixSource
−18.4 ± 1.1 ‰−21.1 / −16.8 ‰21vein and disseminated tourmaline of tuffaceous metavolcanic rocks (type 3) (3_PAMT)
Mean and standard deviation recalculated from 21 analyses, -21.1 to -16.8 (-17.7; -18.4; -18.1; -21.1; -18.2; -19.6; -19.5; -19.9; -19.0; -19.1; -17.5; -17.6; -18.3; -16.8; -18.6; -18.5; -17.7; -18.2; -17.0; -19.3; -17.0). 10 core and 11 rim analyses; published mean -18.4 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …
−20.9 ± 0.9 ‰−22.4 / −19.3 ‰18vein and disseminated tourmaline of tuffaceous metavolcanic rocks (type 3) (4_PAMT)
Mean and standard deviation recalculated from 18 analyses, -22.4 to -19.3 (-21.3; -20.9; -22.4; -21.5; -20.2; -20.5; -21.6; -20.0; -22.3; -20.3; -21.1; -21.5; -21.2; -20.1; -20.0; -19.3; -21.7; -20.4). 10 core and 8 rim analyses; published mean -20.9 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …
−16.2 ± 1.2 ‰−19.4 / −14.5 ‰19vein and disseminated tourmaline of tuffaceous metavolcanic rocks (type 3) (9_PAMT)
Mean and standard deviation recalculated from 19 analyses, -19.4 to -14.5 (-14.7; -16.2; -16.8; -16.4; -16.3; -19.4; -17.5; -16.6; -15.1; -15.9; -15.2; -16.6; -15.6; -15.2; -16.0; -18.1; -14.5; -15.4; -15.5). 12 core and 7 rim analyses; published mean -16.2 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …
−17 ± 1.2 ‰−19 / −14.8 ‰24stockwork tourmaline in an albitized felsic porphyry (type 2) (5_PAMT)
Mean and standard deviation recalculated from 24 analyses, -19.0 to -14.8 (-16.0; -15.6; -17.4; -15.8; -16.2; -18.2; -18.4; -15.9; -18.4; -18.0; -16.0; -15.6; -18.1; -18.3; -16.0; -16.9; -16.5; -19.0; -17.7; -17.5; -16.3; -17.6; -14.8; -18.5). 13 core and 11 rim analyses; published mean -17.0 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …

δ34S in ‰ (per mil) Values of the same system

Standard : V-CDT

ValueRangenMineral or matrixSource
−3.6 ± 2.2 ‰−9.1 / 5.7 ‰175ore pyrite (metavolcanic rocks and porphyries, excluding stockwork 5-PAMT)
Mean and standard deviation recalculated from the means of 21 samples (19802 -0.3 (n = 11); P031200 -2.1 (n = 7); P031210 -3.7 (n = 7); P031228A -2.6 (n = 9); P031224 -1.0 (n = 6); P031242 -6.0 (n = 6); P031243 -6.0 (n = 8); P031259 -1.7 (n = 9); P13061228 -2.3 (n = 4); P031231 -4.3 (n = 11); P13061232 -0.8 (n = 5); 18508 -6.2 (n = 9); 19655 -4.9 (n = 15); 19664 -3.7 (n = 6); 19815 -5.3 (n = 11); 19827 -8.0 (n = 9); P031206 -5.0 (n = 5); P031225B -2.8 (n = 10); P031228B -6.8 (n = 13); 9-PAMT -2.0 (n = 9); GPG-1 -1.1 (n = 5)), i.e. 175 spot analyses from -9.1 to +5.7 ‰. Host rock not stated for most samples; 19827 in a tuffaceous metavolcanic rock, 19802 and P13061232 in feldspar porphyries (Table 5). Negative values: sulphides deposited from more oxidizing fluids according to the authors.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …
3.5 ± 1.2 ‰2.4 / 5.3 ‰7pyrite of the stockwork in a felsic porphyry (5-PAMT)
Published mean and standard deviation of 7 spot analyses (sample 5-PAMT), +2.4 to +5.3 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …
−4.7 ± 0.1 ‰−4.8 / −4.6 ‰3ore pyrrhotite
Published mean and standard deviation of 3 spot analyses (sample P031206), -4.8 to -4.6 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …
−4 ± 2.7 ‰−9 / −0.1 ‰50ore chalcopyrite
Mean and standard deviation recalculated from the means of 6 samples (19802 -0.9 (n = 11); P13061232 -3.1 (n = 3); 19655 -4.9 (n = 11); 19664 -4.4 (n = 7); 19827 -8.6 (n = 7); GPG-1 -1.9 (n = 11)), i.e. 50 spot analyses from -9.0 to -0.1 ‰. For 19664, the published mean (-4.4 ‰) equals the maximum, with a minimum of -5.4 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …

δ65Cu in ‰ (per mil) Values of the same system

Standard : NIST SRM 976

ValueRangenMineral or matrixSource
0.23 ± 0.53 ‰−0.62 / 1.15 ‰17chalcopyrite of metavolcanic rocks (KN19827, KN19664, KN19655)
Mean and standard deviation recalculated from 17 analyses, -0.62 to +1.15 (+0.13; +0.53; +0.46; +0.42; +1.15; +1.03; +0.37; +0.75; +0.43; +0.44; +0.06; +0.41; -0.35; -0.49; -0.28; -0.62; -0.53). Positive values mostly in felsic intrusive rocks, negative in metasediments; no correlation with δ34S according to the authors. Two groups: KN19655 negative (-0.62 to -0.28 ‰), the others positive; δ34S of the same chalcopyrite from -8.7 to -4.6 ‰.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …
0.18 ± 0.44 ‰−0.65 / 1.19 ‰12chalcopyrite of feldspar porphyries (KN19802, P13061232)
Mean and standard deviation recalculated from 12 analyses, -0.65 to +1.19 (+0.18; +1.19; +0.04; +0.48; +0.38; +0.09; +0.21; +0.34; -0.65; +0.10; +0.02; -0.22). Positive values mostly in felsic intrusive rocks, negative in metasediments; no correlation with δ34S according to the authors.
Molnár et al. (2016), Boron, sulphur and copper isotope systematics in the orogenic gold …

Deposits of the same type

Cite this page

IsoFind Atlas (2026). Pampalo (Hattu schist belt), isotope signatures. https://www.isofind.tech/isotopes/en/deposits/pampalo-ceinture-de-hattu/ (accessed 2026-10-19).

@misc{isofind2026pampalohattuschistbeltisotope,
  title = {Pampalo (Hattu schist belt), isotope signatures},
  author = {{IsoFind Atlas}},
  year = {2026},
  url = {https://www.isofind.tech/isotopes/en/deposits/pampalo-ceinture-de-hattu/},
  note = {Accessed 2026-10-19}
}

Updated : 2026-10-19