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Sichuan Devonian phosphates (Shijiao, Hanyuan)

Sichuan, China

OtherP

Type
Marine sedimentary phosphorite (carbonate fluorapatite)

Phosphate rocks studied by Hill et al. (2024) to reconstruct redox conditions and diagenesis: U, Sr and rare earths carried by carbonate fluorapatite; samples taken at mines or from the Julius Kühn Institute archives. Middle to Late Devonian (about 376 Ma); large 234U excess at Hanyuan (δ234U of +116 ‰), uranium remobilised over the last two million years. Coordinates not given.

87Sr/86Sr isotope ratio, no unit Values of the same system

Standard : NIST SRM 987

ValueRangenMineral or matrixSource
0.709644 ± 0.0022580.708047 / 0.7112412phosphate rock (bulk)
Mean and standard deviation recalculated from 2 analyses, samples CN-1, CN-2.
Hill et al. (2024), Reconstructing the depositional environment and diagenetic modificati…
0.7110861extracted carbonate fluorapatite (CFA)
Single analysis; sample CN-2.
Hill et al. (2024), Reconstructing the depositional environment and diagenetic modificati…

δ238U in ‰ (per mil) Values of the same system

Standard : NBL CRM 112-A

ValueRangenMineral or matrixSource
−0.25 ± 0.021 ‰1extracted carbonate fluorapatite (CFA)
Single analysis; sample CN-2; modern seawater at -0.38 ‰ for comparison.
Hill et al. (2024), Reconstructing the depositional environment and diagenetic modificati…

δ234U in ‰ (per mil) Values of the same system

Standard : équilibre séculaire

ValueRangenMineral or matrixSource
115.87 ± 8.33 ‰1extracted carbonate fluorapatite (CFA)
Single analysis; sample CN-2; a departure from 0 signals uranium mobility within the last two million years.
Hill et al. (2024), Reconstructing the depositional environment and diagenetic modificati…

δ18O in ‰ (per mil) Values of the same system

Standard : V-SMOW

ValueRangenMineral or matrixSource
15.13 ± 3.18 ‰12.88 / 17.38 ‰2rock phosphate (PO4 oxygen)
Mean and standard deviation recalculated from 2 analyses, samples CN-1, CN-2.
Hill et al. (2024), Reconstructing the depositional environment and diagenetic modificati…

Deposits of the same type

Cite this page

IsoFind Atlas (2026). Sichuan Devonian phosphates (Shijiao, Hanyuan), isotope signatures. https://www.isofind.tech/isotopes/en/deposits/phosphates-devoniens-du-sichuan-shijiao-hanyuan/ (accessed 2026-10-15).

@misc{isofind2026sichuandevonianphosphatesshij,
  title = {Sichuan Devonian phosphates (Shijiao, Hanyuan), isotope signatures},
  author = {{IsoFind Atlas}},
  year = {2026},
  url = {https://www.isofind.tech/isotopes/en/deposits/phosphates-devoniens-du-sichuan-shijiao-hanyuan/},
  note = {Accessed 2026-10-15}
}

Updated : 2026-10-15