Black Forest hydrothermal veins

Black Forest (Baden-Württemberg), Germany

Other hydrothermalCu (Ag, Bi, Co)

Type
Hydrothermal copper veins (and Pb-Zn-Ag, Co-Ni-Bi)

About twenty vein-type mines of the Black Forest (Dorothea near Freudenstadt, Königswart, Neubulach, Prosper near Rippoldsau, Friedrich-Christian near Schapbach, Wittichen...). Fresh hypogene sulfides have a narrow copper signature close to 0 ‰; oxidation near the surface spreads it widely between residual sulfides and secondary minerals.

δ65Cu in ‰ (per mil) Values of the same system

Standard : NIST SRM 976

ValueRangenMineral or matrixSource
−0.04 ± 0.3 ‰−0.97 / 0.44 ‰27fresh primary sulfides (chalcopyrite, fahlore, emplectite)
Mean and standard deviation of 27 fresh samples. Unaltered hypogene sulfides stay close to 0 ‰.
Markl et al. (2006), Copper isotopes as monitors of redox processes in hydrothermal miner…
−1.22 ± 0.83 ‰−2.85 / −0.04 ‰21partly oxidised primary sulfides
Mean and standard deviation of 21 samples. Oxidation leaves a residual sulfide depleted in 65Cu.
Markl et al. (2006), Copper isotopes as monitors of redox processes in hydrothermal miner…
0.69 ± 0.97 ‰−1.72 / 2.42 ‰30secondary copper minerals (malachite, azurite, cuprite, native copper, olivenite...)
Mean and standard deviation of 30 samples. Secondary minerals cover a wide range, from -1.7 to +2.4 ‰, depending on oxidation and reprecipitation steps.
Markl et al. (2006), Copper isotopes as monitors of redox processes in hydrothermal miner…

δ56Fe in ‰ (per mil) Values of the same system

Standard : IRMM-014

ValueRangenMineral or matrixSource
−0.91 ± 0.22 ‰−1.36 / −0.73 ‰7siderite
Mean and standard deviation of 7 analyses.
Markl et al. (2006), Iron isotope fractionation during hydrothermal ore deposition and al…
0.06 ± 0.31 ‰−0.49 / 0.56 ‰13primary hematite
Mean and standard deviation of 13 analyses.
Markl et al. (2006), Iron isotope fractionation during hydrothermal ore deposition and al…
−0.82 ± 0.39 ‰−1.48 / −0.24 ‰9secondary hematite
Mean and standard deviation of 9 analyses.
Markl et al. (2006), Iron isotope fractionation during hydrothermal ore deposition and al…
−0.73 ± 0.23 ‰−1.13 / −0.51 ‰6secondary goethite
Mean and standard deviation of 6 analyses.
Markl et al. (2006), Iron isotope fractionation during hydrothermal ore deposition and al…
−0.23 ± 0.16 ‰−0.34 / 0.01 ‰4sulfides (pyrite, chalcopyrite)
Mean and standard deviation of 4 analyses.
Markl et al. (2006), Iron isotope fractionation during hydrothermal ore deposition and al…

Deposits of the same type

Cite this page

IsoFind Atlas (2026). Black Forest hydrothermal veins, isotope signatures. https://www.isofind.tech/isotopes/en/deposits/filons-hydrothermaux-de-foret-noire/ (accessed 2026-10-06).

@misc{isofind2026blackforesthydrothermalveinsi,
  title = {Black Forest hydrothermal veins, isotope signatures},
  author = {{IsoFind Atlas}},
  year = {2026},
  url = {https://www.isofind.tech/isotopes/en/deposits/filons-hydrothermaux-de-foret-noire/},
  note = {Accessed 2026-10-06}
}

Updated : 2026-10-06